{"id":3770,"date":"2013-08-17T14:59:57","date_gmt":"2013-08-17T18:59:57","guid":{"rendered":"http:\/\/catalysisclubphilly.org\/?p=3770"},"modified":"2013-08-17T15:50:09","modified_gmt":"2013-08-17T19:50:09","slug":"kinetics-and-mechanisms-of-c-c-forming-and-c-o-cleavage-reactions","status":"publish","type":"post","link":"https:\/\/catalysisclubphilly.org\/awe9a91v\/meetings\/kinetics-and-mechanisms-of-c-c-forming-and-c-o-cleavage-reactions\/","title":{"rendered":"Kinetics and Mechanisms of C-C Forming and C-O Cleavage Reactions of Interests in Bio-oil Upgrading"},"content":{"rendered":"<h3>Meeting Program \u2014 September 2013<\/h3>\n<p>&nbsp;<br>\n<strong>Daniel E. Resas\u00adco<\/strong><br>\n<em>Uni\u00adver\u00adsi\u00adty of Okla\u00adhoma<br>\nNor\u00adman, OK<\/em><br>\n&nbsp;<br>\n<strong>Abstract<\/strong> \u2014 Bio-oil pro\u00adduced by fast pyrol\u00ady\u00adsis of lig\u00adno\u00adcel\u00adlu\u00adlosic bio\u00admass has attract\u00aded con\u00adsid\u00ader\u00adable atten\u00adtion as an inter\u00adme\u00addi\u00adate liq\u00aduid prod\u00aduct towards the pro\u00adduc\u00adtion of fuels. How\u00adev\u00ader its chem\u00adi\u00adcal insta\u00adbil\u00adi\u00adty, high vis\u00adcos\u00adi\u00adty, and cor\u00adro\u00adsive\u00adness lim\u00adit their process\u00adabil\u00adi\u00adty and stor\u00adage. One of the great\u00adest chal\u00adlenges in the upgrad\u00ading of bio-oil is the accel\u00ader\u00adat\u00aded degra\u00adda\u00adtion that occurs when the con\u00addensed liq\u00aduid is sub\u00adse\u00adquent\u00adly heat\u00aded for frac\u00adtion\u00ada\u00adtion or oth\u00ader pro\u00adcess\u00ading. Cat\u00adalyt\u00adic upgrad\u00ading is an attrac\u00adtive strat\u00ade\u00adgy that can be used to opti\u00admize car\u00adbon effi\u00adcien\u00adcy and min\u00adi\u00admize hydro\u00adgen usage. Impor\u00adtant reac\u00adtions for this upgrad\u00ading include:<\/p>\n<ul>\n<li>For\u00adma\u00adtion of C-C bonds to extend the car\u00adbon back\u00adbone of short oxy\u00adgenates to the desired gasoline\/diesel range via aldol con\u00adden\u00adsa\u00adtion and ketoniza\u00adtion in aque\u00adous phase<\/li>\n<li>Incor\u00adpo\u00adra\u00adtion of short car\u00adbon frag\u00adments (C1-C3) into the aro\u00admat\u00adic ring of phe\u00adno\u00adlic com\u00adpounds via alky\u00adla\u00adtion in bipha\u00adsic sys\u00adtems<\/li>\n<li>Deoxy\u00adgena\u00adtion of the result\u00ading prod\u00aducts to mono\u00adfunc\u00adtion\u00adal com\u00adpounds or hydro\u00adcar\u00adbons in the liq\u00aduid phase.<\/li>\n<\/ul>\n<p>We have inves\u00adti\u00adgat\u00aded the kinet\u00adics and reac\u00adtion mech\u00ada\u00adnisms of these reac\u00adtions on dif\u00adfer\u00adent cat\u00ada\u00adlysts, includ\u00ading met\u00adals sup\u00adport\u00aded on reducible oxides (e.g. Ru\/TiO<sub>2<\/sub>); acidic cat\u00ada\u00adlysts (HY, H-beta zeo\u00adlites), sup\u00adport\u00aded met\u00adal cat\u00ada\u00adlysts (Cu, Ni, Ru, Pd sup\u00adport\u00aded on car\u00adbon nan\u00adotubes) and amphiphilic nanopar\u00adti\u00adcle cat\u00ada\u00adlysts that are able sta\u00adbi\u00adlize water\/oil emul\u00adsions and to con\u00adduct reac\u00adtions at the liquid\/liquid inter\u00adface to ben\u00ade\u00adfit from the dif\u00adfer\u00adences in sol\u00adu\u00adbil\u00adi\u00adty exhib\u00adit\u00aded by the reac\u00adtants (bio-oil) and prod\u00aducts (bio-fuels) and achieve con\u00adtin\u00adu\u00adous reaction\/separation.<br>\n&nbsp;<br>\n<strong>Ref\u00ader\u00adences<\/strong><\/p>\n<ol>\n<li><span class=\"dquo\">\u201c<\/span>Improv\u00ading car\u00adbon reten\u00adtion in bio\u00admass con\u00adver\u00adsion by alky\u00adla\u00adtion \u2026\u201d Appl. Catal. A 447, 14, 2012.<\/li>\n<li><span class=\"dquo\">\u201c<\/span>Aque\u00adous Phase Ketoniza\u00adtion of Acetic Acid over Ru\/TiO2\/Carbon Cat\u00ada\u00adlysts\u201d J. Catal. 295, 169, 2012.<\/li>\n<li><span class=\"dquo\">\u201c<\/span>Hydropho\u00adbic zeo\u00adlites for bio\u00adfu\u00adel upgrad\u00ading at the liq\u00aduid-liq\u00aduid inter\u00adface \u2026 JACS134, 8570, 2012.<\/li>\n<li><span class=\"dquo\">\u201c<\/span>What Should We Demand from the Cat\u00ada\u00adlysts Respon\u00adsi\u00adble for Upgrad\u00ading Bio\u00admass?\u201d J. Phys. Chem. Lett., 2, 2294, 2011.<\/li>\n<li><span class=\"dquo\">\u201c<\/span>Selec\u00adtive Con\u00adver\u00adsion of Fur\u00adfur\u00adal to Methyl\u00adfu\u00adran over Ni-Fe Cat\u00ada\u00adlysts,\u201d J. Catal. 284, 90, 2011.<\/li>\n<li><span class=\"dquo\">\u201c<\/span>Bifunc\u00adtion\u00adal transalky\u00adla\u00adtion and hydrodeoxy\u00adgena\u00adtion of anisole over Pt\/HBeta,\u201d J. Catal. 281, 21, 2011.<\/li>\n<li><span class=\"dquo\">\u201c<\/span>Con\u00adver\u00adsion of fur\u00adfur\u00adal and 2-methylpen\u00adtanal on Pd\u2013Cu cat\u00ada\u00adlysts\u201d J. Catal. 280, 17, 2011.<\/li>\n<p>catalys isclubphi l ly\u200b.org<\/p>\n<li><span class=\"dquo\">\u201c<\/span>Kinet\u00adics and mech\u00ada\u00adnism of hydro\u00adgena\u00adtion of fur\u00adfur\u00adal on Cu cat\u00ada\u00adlysts,\u201d J. Catal. 277, 1, 2011.<\/li>\n<li><span class=\"dquo\">\u201c<\/span>Role of transalky\u00adla\u00adtion in the con\u00adver\u00adsion of anisole over HZSM-5,\u201d Appl. Catal. A, 379, 172, 2010.<\/li>\n<li><span class=\"dquo\">\u201c<\/span>Sol\u00adid Nanopar\u00adti\u00adcles that Cat\u00adalyze Bio\u00adfu\u00adel Upgrade at the Water-Oil Inter\u00adface, \u201d Sci\u00adence, 327, 68, 2010.<\/li>\n<\/ol>\n<p>&nbsp;<br>\n<a href=\"http:\/\/catalysisclubphilly.org\/news\/daniel-resasco-is-the-recipient-of-the-2013-catalysis-club-of-philadelphia-award\/attachment\/daniel_resasco\/\" rel=\"attachment wp-att-3786\"><img loading=\"lazy\" decoding=\"async\" src=\"http:\/\/catalysisclubphilly.org\/awe9a91v\/uploads\/2013\/08\/Daniel_Resasco-214x300.jpg\" alt=\"Daniel_Resasco\" width=\"214\" height=\"300\" class=\"alignleft size-medium wp-image-3786\" srcset=\"https:\/\/catalysisclubphilly.org\/uploads\/2013\/08\/Daniel_Resasco-214x300.jpg 214w, https:\/\/catalysisclubphilly.org\/uploads\/2013\/08\/Daniel_Resasco-207x290.jpg 207w, https:\/\/catalysisclubphilly.org\/uploads\/2013\/08\/Daniel_Resasco.jpg 343w\" sizes=\"auto, (max-width: 214px) 100vw, 214px\"><\/a><strong>Biog\u00adra\u00adphy<\/strong> \u2014 Daniel E. Resas\u00adco is a Pro\u00adfes\u00adsor of Chem\u00adi\u00adcal, Bio\u00adlog\u00adi\u00adcal, and Mate\u00adri\u00adals Engi\u00adneer\u00ading at the Uni\u00adver\u00adsi\u00adty of Okla\u00adhoma. He holds the D. Bourne endowed Chair. He received his PhD from Yale Uni\u00adver\u00adsi\u00adty in 1983. He is author of more than 200 pub\u00adli\u00adca\u00adtions and 35 indus\u00adtri\u00adal patents in the areas of het\u00adero\u00adge\u00adneous catal\u00ady\u00adsis and car\u00adbon nan\u00adotubes and has received more than 8,000 cita\u00adtions. He has been a Pres\u00adi\u00adden\u00adtial Pro\u00adfes\u00adsor, S. Wil\u00adson Pro\u00adfes\u00adsor, and in the last few years he was award\u00aded the Okla\u00adhoma Chemist of the Year award by the Amer\u00adi\u00adcan Chem\u00adi\u00adcal Soci\u00adety, the Yale Sci\u00adence and Engi\u00adneer\u00ading Asso\u00adci\u00ada\u00adtion award, and the Regents Award for Supe\u00adri\u00ador Research. He is the founder of South\u00adWest Nan\u00adotech\u00adnolo\u00adgies, a com\u00admer\u00adcial car\u00adbon nan\u00adotube pro\u00adduc\u00ader that oper\u00adates in Nor\u00adman, OK. He has been Edi\u00adtor of the Jour\u00adnal of Catal\u00ady\u00adsis, and has been a mem\u00adber of the edi\u00adto\u00adr\u00adi\u00adal board of Applied Catal\u00ady\u00adsis and Jour\u00adnal of Catal\u00ady\u00adsis.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Meet\u00ading Pro\u00adgram \u2014 Sep\u00adtem\u00adber 2013 &nbsp; Daniel E. Resas\u00adco Uni\u00adver\u00adsi\u00adty of Okla\u00adhoma Nor\u00adman, OK &nbsp; Abstract \u2014 Bio-oil pro\u00adduced by fast pyrol\u00ady\u00adsis of lig\u00adno\u00adcel\u00adlu\u00adlosic bio\u00admass has attract\u00aded con\u00adsid\u00ader\u00adable atten\u00adtion as an inter\u00adme\u00addi\u00adate liq\u00aduid prod\u00aduct towards the pro\u00adduc\u00adtion of fuels. How\u00adev\u00ader its chem\u00adi\u00adcal insta\u00adbil\u00adi\u00adty, high vis\u00adcos\u00adi\u00adty, and cor\u00adro\u00adsive\u00adness lim\u00adit their process\u00adabil\u00adi\u00adty and stor\u00adage. One of the [\u2026]<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"ngg_post_thumbnail":0,"footnotes":""},"categories":[15,13],"tags":[],"class_list":["post-3770","post","type-post","status-publish","format-standard","hentry","category-abstracts","category-meetings"],"_links":{"self":[{"href":"https:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/posts\/3770","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/comments?post=3770"}],"version-history":[{"count":9,"href":"https:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/posts\/3770\/revisions"}],"predecessor-version":[{"id":3789,"href":"https:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/posts\/3770\/revisions\/3789"}],"wp:attachment":[{"href":"https:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/media?parent=3770"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/categories?post=3770"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/tags?post=3770"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}