Reactive boiling of microcrystalline cellulose on high-temperature inorganic surfaces for millisecond processes

2010 Spring Symposium

 
Paul J. Dauen­hauer
Uni­ver­si­ty of Mass­a­chu­setts, Amherst


Abstract — Par­ti­cles of micro­crys­talline cel­lu­lose approx­i­mate­ly 300 µm in diam­e­ter ther­mal­ly decom­pose on high tem­per­a­ture (700 °C) inor­gan­ic sur­faces coat­ed with Rh-based reform­ing cat­a­lyst to an inter­me­di­ate liq­uid. The inter­me­di­ate liq­uid main­tains con­tact with the sur­face per­mit­ting high heat trans­fer which results in an inter­nal ther­mal gra­di­ent with­in the par­ti­cle. Con­ver­sion from sol­id to liq­uid occurs along the inter­nal ther­mal gra­di­ent final­ly result­ing in a ful­ly liq­uid droplet which com­plete­ly boils to vapors.

Speaker’s Biog­ra­phy — Paul Dauen­hauer is an assis­tant pro­fes­sor of Chem­i­cal Engi­neer­ing at the Uni­ver­si­ty of Mass­a­chu­setts, Amherst. His research cur­rent­ly exam­ines the chem­istry of bio­mass pyrol­y­sis in the pres­ence of reform­ing and com­bus­tion cat­a­lysts. He was for­mer­ly a Senior Research Engi­neer with the Dow Chem­i­cal Com­pa­ny in Mid­land, MI, and Freeport, TX, as part of both Core R&D – Reac­tion Engi­neer­ing and Chem­istry and Catal­y­sis, as well as the Hydro­car­bons and Ener­gy R&D divi­sion. He was the co-inven­tor of the process Reac­tive Flash Volatiliza­tion for the con­ver­sion of bio­mass to syn­the­sis gas at mil­lisec­ond res­i­dence times, and he cur­rent­ly is a co-author of four patent appli­ca­tions relat­ed to cat­alyt­ic bio­mass pro­cess­ing. For­mer employ­ment includ­ed Cargill, Inc. at Gainesville, GA, as part of the Grain & Oilseeds Divi­sion as well as Wah­peton, ND, as part of the Sweet­en­ers divi­sion for the wet milling of maize.