{"id":4974,"date":"2018-04-15T22:02:09","date_gmt":"2018-04-16T02:02:09","guid":{"rendered":"http:\/\/catalysisclubphilly.org\/?p=4974"},"modified":"2018-04-15T22:02:09","modified_gmt":"2018-04-16T02:02:09","slug":"commercial-perspective-alternative-routes-acrylic-acid-monomer","status":"publish","type":"post","link":"http:\/\/catalysisclubphilly.org\/awe9a91v\/abstracts\/commercial-perspective-alternative-routes-acrylic-acid-monomer\/","title":{"rendered":"Commercial Perspective of Alternative Routes to Acrylic Acid Monomer"},"content":{"rendered":"<h3>2018 Spring Symposium<\/h3>\n<p><strong>Jin\u00adsuo Xu<\/strong>, <em>The Dow Chem\u00adi\u00adcal Com\u00adpa\u00adny, 400 Arco\u00adla Rd, Col\u00adlegeville, PA 19426<\/em> <\/p>\n<p><strong>Abstract<\/strong> \u2014 Acrylic acid and cor\u00adre\u00adspond\u00ading acry\u00adlates are major monomers for a vari\u00adety of func\u00adtion\u00adal poly\u00admers used broad\u00adly in our dai\u00adly life such as coat\u00ading, sealant, and per\u00adson\u00adal care. The two-stage selec\u00adtive oxi\u00adda\u00adtion of propy\u00adlene to acrolein and then to acrylic acid was first com\u00admer\u00adcial\u00adized in ear\u00adly 70s and quick\u00adly became the dom\u00adi\u00adnant route to acrylic acid. Dri\u00adven by feed\u00adstock cost or avail\u00adabil\u00adi\u00adty or sus\u00adtain\u00adabil\u00adi\u00adty, sig\u00adnif\u00adi\u00adcant efforts from both indus\u00adtry and acad\u00ade\u00admia were devot\u00aded to devel\u00adop\u00ading alter\u00adna\u00adtive routes to acrylic acid. Cat\u00ada\u00adlyst plays crit\u00adi\u00adcal role in the key step of trans\u00adform\u00ading dif\u00adfer\u00adent raw mate\u00adr\u00adi\u00adal into prod\u00aduct effec\u00adtive\u00adly, for exam\u00adple, mixed met\u00adal oxides MoVTeN\u00adbO<sub>x<\/sub> in propane selec\u00adtive oxi\u00adda\u00adtion, sol\u00adid acids in dehy\u00addra\u00adtion of glyc\u00aderin or 3-HP, and var\u00adi\u00adous oxides in aldol con\u00adden\u00adsa\u00adtion of acetic acid and formalde\u00adhyde. This pre\u00adsen\u00adta\u00adtion will dis\u00adcuss the progress of these major routes, the chal\u00adlenges towards com\u00admer\u00adcial\u00adiza\u00adtion, and poten\u00adtial solu\u00adtions.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>2018 Spring Sym\u00adpo\u00adsium Jin\u00adsuo Xu, The Dow Chem\u00adi\u00adcal Com\u00adpa\u00adny, 400 Arco\u00adla Rd, Col\u00adlegeville, PA 19426 Abstract \u2014 Acrylic acid and cor\u00adre\u00adspond\u00ading acry\u00adlates are major monomers for a vari\u00adety of func\u00adtion\u00adal poly\u00admers used broad\u00adly in our dai\u00adly life such as coat\u00ading, sealant, and per\u00adson\u00adal care. The two-stage selec\u00adtive oxi\u00adda\u00adtion of propy\u00adlene to acrolein and then to [\u2026]<\/p>\n","protected":false},"author":5,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"ngg_post_thumbnail":0,"footnotes":""},"categories":[15,8],"tags":[],"class_list":["post-4974","post","type-post","status-publish","format-standard","hentry","category-abstracts","category-news"],"_links":{"self":[{"href":"http:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/posts\/4974","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"http:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/comments?post=4974"}],"version-history":[{"count":1,"href":"http:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/posts\/4974\/revisions"}],"predecessor-version":[{"id":4975,"href":"http:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/posts\/4974\/revisions\/4975"}],"wp:attachment":[{"href":"http:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/media?parent=4974"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/categories?post=4974"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/catalysisclubphilly.org\/awe9a91v\/wp-json\/wp\/v2\/tags?post=4974"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}